The emission properties of PbTe(111) single crystal have been extensively investigated to demonstrate that PbTe(111) is a promising low root mean square transverse momentum (ΔpT) and high brightness photocathode. The density functional theory (DFT) based photoemission analysis successfully elucidates that the 'hole-like' Λ6+ energy band in the L
Nearby in the stack
valley with low effective mass
m∗
results in low Δp
T
. Especially, as a 300K solid planar photocathode, Te-terminated PbTe(111) single crystal is expected to be a potential 50K electron source.